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Acetic acid,tin(2+) salt

Tin(II) acetate

CAS: 638-39-1

Molecular Formula: C4H6O4Sn

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Acetic acid,tin(2+) salt - Names and Identifiers

Name Tin(II) acetate
Synonyms Tin ii acetate
tin di(acetate)
Tin(II) acetate
Stannous acetate
TIN (II) ACETATE
STANNOUS ACETATE
tin(2+) diacetate
Tin(II) acetate,pure
Acetic acid,tin(2+) salt
Diacetic acid tin(II) salt
TinIIacetateoffwhitepowder
CAS 638-39-1
EINECS 211-335-9
InChI InChI=1/2C2H4O2.Sn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

Acetic acid,tin(2+) salt - Physico-chemical Properties

Molecular FormulaC4H6O4Sn
Molar Mass236.8
Density2,31 g/cm3
Melting Point180-182°C(lit.)
Boling Point155°C 0,1mm
Flash Point40°C
Water SolubilityDecomposes in water. Soluble in dilute HClSoluble in dilute hydrochloric acid, dimethyl sulfoxide and methanol.
Vapor Presure13.9mmHg at 25°C
AppearancePowder
Specific Gravity2.11
ColorWhite
Exposure LimitACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Merck14,8781
Storage ConditionInert atmosphere,Room Temperature
Sensitive7: reacts slowly with moisture/water
MDLMFCD00054408

Acetic acid,tin(2+) salt - Risk and Safety

Hazard SymbolsXn - Harmful
Harmful
Risk Codes20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
Safety Description36 - Wear suitable protective clothing.
UN IDsUN 3146 6.1/PG 3
WGK Germany3
TSCANo
Hazard Class6.1
Packing GroupIII

Acetic acid,tin(2+) salt - Reference Information

Use hydrocarbon propyl propionate is commonly used as an intermediate in organic synthesis, and can be used in laboratory research and development process.
preparation a process for preparing stannous acetate (propyl hydrocarbon propionate), comprising the following specific steps:
(1) weigh stannous oxide, weigh deionized water according to the mass ratio of stannous oxide of 1-2 ∶ 1, and add to the reaction kettle;
(2) turn on the stirring, slowly add stannous oxide weighed in step (1);
(3) raise the temperature, gradually add glacial acetic acid solution until the temperature rises to 75-85 ℃, stir while adding, complete feeding within 30min;
(4) continue to heat up to 95-100 ℃ for 3H;
(6) maintain the temperature at 100 ℃, vacuum distillation, to no low boiling material distillation, after the material is white solid, the distillation is stopped;
(6) the machine is stopped, the product is taken out, pulverized and dried in an oven at 100 ° C. To obtain the desired stannous acetate (propyl hydrocarbon propionate) product.
Last Update:2024-04-10 22:29:15
Acetic acid,tin(2+) salt
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Acetic acid,tin(2+) salt
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